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Abstract Soils are a principal global reservoir of mercury (Hg), a neurotoxic pollutant that is accumulating through anthropogenic emissions to the atmosphere and subsequent deposition to terrestrial ecosystems. The fate of Hg in global soils remains uncertain, however, particularly to what degree Hg is re-emitted back to the atmosphere as gaseous elemental mercury (GEM). Here we use fallout radionuclide (FRN) chronometry to directly measure Hg accumulation rates in soils. By comparing these rates with measured atmospheric fluxes in a mass balance approach, we show that representative Arctic, boreal, temperate, and tropical soils are quantitatively efficient at retaining anthropogenic Hg. Potential for significant GEM re-emission appears limited to a minority of coniferous soils, calling into question global models that assume strong re-emission of legacy Hg from soils. FRN chronometry poses a powerful tool to reconstruct terrestrial Hg accumulation across larger spatial scales than previously possible, while offering insights into the susceptibility of Hg mobilization from different soil environments. 

Amplified warming of high latitudes and rapid thaw of frozen ground threaten permafrost carbon stocks. The presence of permafrost modulates water infiltration and flow, as well as sediment transport, on soil-mantled slopes, influencing the balance of advective fluvial processes to diffusive processes on hillslopes in ways that are different from temperate settings. These processes that shape permafrost landscapes also impact the carbon stored on soil-mantled hillslopes via temperature, saturation, and slope stability such that carbon stocks and landscape morphometry should be closely linked. We studied $>$69,000 headwater basins between 25° and 90 °N to determine whether the thermal state of the soil sets the balance between hillslope (diffusive) and fluvial (advective) erosion processes, as evidenced by the density of the channel networks (i.e., drainage density) and the proportion of convex to concave topography (hillslopes and river valleys, respectively). Watersheds within permafrost regions have lower drainage densities than regions without permafrost, regardless of watershed glacial history, mean annual precipitation, and relief. We find evidence that advective fluvial processes are inhibited in permafrost landscapes compared to their temperate counterparts. Frozen soils likely inhibit channel development, and we predict that climate warming will lower incision thresholds to promote growth of the channel network in permafrost landscapes. By demonstrating how the balance of advective versus diffusive processes might shift with future warming, we gain insight into the mechanisms that shift these landscapes from sequestering to exporting carbon.